• 文献标题:   Rapid removal of trace haloacetic acids from drinking water by a continuous adsorption process using graphene oxide
  • 文献类型:   Article, Early Access
  • 作  者:   LIU ZM, ZHANG ZR, PENG JW, WU JH, HUO Y
  • 作者关键词:   graphene oxide, haloacetic acid, continuous adsorption, rapid removal, drinking water
  • 出版物名称:   ENVIRONMENTAL TECHNOLOGY
  • ISSN:   0959-3330 EI 1479-487X
  • 通讯作者地址:   Northeast Normal Univ
  • 被引频次:   0
  • DOI:   10.1080/09593330.2020.1841307 EA NOV 2020
  • 出版年:  

▎ 摘  要

Significant health risks are caused by trace levels of haloacetic acids (HAAs) in drinking water. We used graphene oxide (GO), a high-performance absorbent, to remove monochloroacetic acid (MCAA), dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA). 31.6%, 27.1% and 30.2% of MCAA, DCAA and TCAA in drinking water could be rapidly removed within 2 min by the interaction of intermolecular hydrogen bonds between GO and HAAs. On the other hand, as a type of weak interaction, intermolecular hydrogen bonds are easy to fracture, which leads to the recovery of GO. The removal efficiency of MCAA, DCAA and TCAA monotonously decreased with increasing pH from 3 to 11. Temperature was not an important influence on the removal efficiency of HAAs, and only affected the interaction of intermolecular hydrogen bonds between GO and HAAs. A continuous adsorption process was used for further improving the removal efficiency of HAAs, and the concentration of total HAAs decreased from 436 to 52.5 mu g L-1 after five adsorption processes. The total contact time was just 2.25 min, which was faster than other reported adsorbents, and total HAAs could be decreased by 88%. The innovative process in this study provides an effective method for application of GO to rapidly remove HAAs in drinking water.