• 文献标题:   Possibility of graphene growth by close space sublimation
  • 文献类型:   Article
  • 作  者:   SOPINSKYY MV, KHOMCHENKO VS, STRELCHUK VV, NIKOLENKO AS, OLCHOVYK GP, VISHNYAK VV, STONIS VV
  • 作者关键词:   graphene film, deposition, graphite, sublimation, si/sio2 substrate, raman spectroscopy, ellipsometry
  • 出版物名称:   NANOSCALE RESEARCH LETTERS
  • ISSN:   1931-7573 EI 1556-276X
  • 通讯作者地址:   Natl Acad Sci Ukraine
  • 被引频次:   7
  • DOI:   10.1186/1556-276X-9-182
  • 出版年:   2014

▎ 摘  要

Carbon films on the Si/SiO2 substrate are fabricated using modified method of close space sublimation at atmospheric pressure. The film properties have been characterized by micro-Raman and X-ray photoelectron spectroscopy and monochromatic ellipsometry methods. Ellipsometrical measurements demonstrated an increase of the silicon oxide film thickness in the course of manufacturing process. The XPS survey spectra of the as-prepared samples indicate that the main elements in the near-surface region are carbon, silicon, and oxygen. The narrow-scan spectra of C1s, Si2p, O1s regions indicate that silicon and oxygen are mainly in the SiO (x) (x a parts per thousand aEuro parts per thousand 2) oxide form, whereas the main component of C1s spectrum at 284.4 eV comes from the sp (2)-hybridized carbon phase. Micro-Raman spectra confirmed the formation of graphene films with the number of layers that depended on the distance between the graphite source and substrate.