• 文献标题:   Analysis of the dielectric relaxation in reduced graphene oxide/epoxy composites materials using the modulus formalism
  • 文献类型:   Article
  • 作  者:   NIOUA Y, MELO BMG, PREZAS P, GRACA MF, ACHOUR ME, COSTA LC
  • 作者关键词:  
  • 出版物名称:   EUROPEAN PHYSICAL JOURNAL E
  • ISSN:   1292-8941 EI 1292-895X
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1140/epje/s10189-021-00109-7
  • 出版年:   2021

▎ 摘  要

This work reports an analysis of the dielectric properties of reduced graphene oxide mixed into epoxy resin, diglycidyl ether of bisphenol A, in the frequency range 10(2)-10(6) Hz and over the temperature range of 300-400 K, using impedance spectroscopy. For this study, a series of samples were prepared with various filler contents. Using the electric modulus formalism, it has been found that these composites exhibit below and above the percolation threshold phi(c) a critical behavior of the dielectric relaxation phenomenon due to the single alpha-relaxation, which is associated with the glass-rubbery transition of the epoxy matrix above the glass transition temperature. The Cole-Cole model of dielectric relaxation was used for modeling the relaxation processes from which we extract the relaxation parameters. The obtained relaxation parameters suggest a behavior close to single relaxation time.