• 文献标题:   Hydrofluorinated graphene: Two-dimensional analog of polyvinylidene fluoride
  • 文献类型:   Article
  • 作  者:   SINGH R, BESTER G
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   1098-0121
  • 通讯作者地址:   Max Planck Inst Festkorperforsch
  • 被引频次:   24
  • DOI:   10.1103/PhysRevB.84.155427
  • 出版年:   2011

▎ 摘  要

We suggest theoretically the existence of a stoichiometric derivative of graphene, a two-dimensional analog of polyvinylidene fluoride, with fluorine and hydrogen atoms alternately attached to carbon atoms in a chairlike configuration. Analyzing the different possible decorations of H and F of graphene, we find that all are unstable but one. This low-energy structure has a wide band gap and an elastic strength comparable to that of pristine graphene. One other structure is shown to become stable under compressive stress.