• 文献标题:   Surface characterization of graphene based materials
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   PISAREK M, HOLDYNSKI M, KRAWCZYK M, NOWAKOWSKI R, ROGUSKA A, MALOLEPSZY A, STOBINSKI L, JABLONSKI A
  • 作者关键词:   graphene, reduced graphene oxide rgo, elasticpeak electron spectroscopy epes, electron inelastic mean free path imfp, surface analysis aes reels xps
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Polish Acad Sci
  • 被引频次:   5
  • DOI:   10.1016/j.apsusc.2016.02.169
  • 出版年:   2016

▎ 摘  要

In the present study, two kind of samples were used: (i) a monolayer graphene film with a thickness of 0.345 nm deposited by the CVD method on Cu foil, (ii) graphene flakes obtained by modified Hummers method and followed by reduction of graphene oxide. The inelastic mean free path (IMFP), characterizing electron transport in graphene/Cu sample and reduced graphene oxide material, which determines the sampling depth of XPS and AES were evaluated from relative Elastic Peak Electron Spectroscopy (EPES) measurements with the Au standard in the energy range 0.5-2 keV. The measured IMFPs were compared with IMFPs resulting from experimental optical data published in the literature for the graphite sample. The EPES IMFP values at 0.5 and 1.5 keV was practically identical to that calculated from optical data for graphite (less than 4% deviation). For energies 1 and 2 keV, the EPES IMFPs for rGO were deviated up to 14% from IMFPs calculated using the optical data by Tanuma et al. [1]. Before EPES measurements all samples were characterized by various techniques like: FE-SEM, AFM, XPS, AES and REELS to visualize the surface morphology/topography and identify the chemical composition. (C) 2016 Elsevier B.V. All rights reserved.