• 文献标题:   Graphene/polypropylene nanocomposites with improved thermal and mechanical properties
  • 文献类型:   Article
  • 作  者:   ABUOUDAH CK, GREISH YE, ABUJDAYIL B, ELSAID EM, IQBAL MZ
  • 作者关键词:   graphene, extrusion, mechanical propertie, nanotube, thermal propertie, thermoplastic
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   United Arab Emirates Univ
  • 被引频次:   0
  • DOI:   10.1002/app.50024 EA OCT 2020
  • 出版年:   2021

▎ 摘  要

Small amount of large surface area graphene (G) is expected to significantly alter functional properties of polymers. The property enhancement is a function of degree of exfoliation and dispersion of G as well as its compatibility with base polymer. However, nonpolar nature of polyolefins such as polypropylene (PP) restricts homogeneous dispersion of G, leading to significant agglomeration and properties reduction. In this work, two compatibilizers, poly (ethylene-co-butyl acrylate) (EBA) (new compatibilizer) and PP-grafted-maleic anhydride (MA-PP) (conventional compatibilizer) were compared to enhance the dispersion efficacy of G in PP. The EBA-compatibilized nanocomposites exhibited 44% increase in the Young's modulus compared to 32% increment in MA-PP-compatibilized nanocomposites. Higher elongation at break for EBA-compatibilized nanocomposites is attributed to lower degree of crystallinity in these nanocomposites. On the other hand, EBA-compatibilized nanocomposites showed significantly improved thermal stability compared to MA-PP-compatibilized nanocomposites. The results indicate that EBA may act as a potential compatibilizer for G/PP nanocomposites.