• 文献标题:   Single Non-Blinking Graphene Quantum Dots Identified by Single-Particle Catalysis
  • 文献类型:   Article, Early Access
  • 作  者:   FU W, CAO HQ, CHEETHAM AK
  • 作者关键词:   antibunching, catalytic reaction, graphene quantum dot, nonblinking, single quantum dot
  • 出版物名称:   ADVANCED OPTICAL MATERIALS
  • ISSN:   2195-1071
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/adom.202300434 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Quantum dots (QDs) with non-blinking applied in bio-imaging is important for understanding cellular dynamics by monitoring single particles in living cells. Antibunching is once believed to be applied to identify a single QD, which shows a strong dependence on the atom or ion number. However, recent works indicate that the antibunching alone may not be sufficient to demonstrate that the fluorescence comes from a single QD. To some extent, it is neither necessary nor sufficient for a single QD, though it is absolutely right for a single atom because a single QD is composed of thousands of atoms, which in principle are favorable to the formation of multi-excitonic states. Blinking behavior, almost unobservable in ensembles due to the averaging, is characteristic of the single QD which owns the quantum effect due to its discrete energy levels. Here, a method of transformation of a single graphene quantum dot from non-blinking to blinking via catalytic reaction to identify a single QD is reported, which can also help with understanding the catalytic dynamics of a single QD, which is a complementary means of confirming a single QD. The reported technique paves the way to understanding a single QD and its catalytic and kinetic behaviors.