• 文献标题:   Effects of carbon nanotubes, graphene and titanium suboxides on electrochemical properties of V2Al1-xCTz ceramic as an anode for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LIU RJ, YANG LX, WANG Y, LIU HJ, ZHANG X, ZENG CL
  • 作者关键词:   v2al1xctz, ceramic, carbon nanotube, ti4o7, graphene, lithium ion batterie
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.ceramint.2021.09.050 EA OCT 2021
  • 出版年:   2021

▎ 摘  要

Partially-etched V2Al1-xCTz ceramic with the average particle of -400 nm was synthesized by etching submicrosized V2AlC with 40 wt% HF at room temperature (RT) for 48 h and 72 h, respectively. V2Al1-xCTz etched for 72 h has exhibited higher charge-discharge property, with an average reversible discharge capacity of 349.2 mAh center dot g-1 at 0.1 A g-1 in the 120 cycles for lithium-ion batteries. The electrochemical performances of V2Al1-xCTz could be improved by the addition of carbon nanotubes (CNTs), graphene (GF) and titanium suboxides (Ti4O7) conductive additives, among which CNTs exhibit the best effectiveness with a capacity of -460 mAh center dot g-1 at 0.1 A g-1 in the 140 cycles and a capacity retention of -72% at 0.5 A g-1 after 400 cycles.