• 文献标题:   Porous interconnected NiCo2O4 nanosheets and nitrogen- and sulfur-codoped reduced graphene oxides for high-performance hybrid supercapacitors
  • 文献类型:   Article
  • 作  者:   SIVAKUMAR P, JANA M, KOTA M, LEE HS, PARK HS
  • 作者关键词:   nickel cobalt oxide, 2d nanomaterial, hybrid supercapacitor, doped graphene
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   11
  • DOI:   10.1016/j.jallcom.2018.12.013
  • 出版年:   2019

▎ 摘  要

We demonstrate a facile hydrothermal synthesis of the interconnected porous NiCo2O4 nanosheets for hybrid supercapacitor applications. The as-synthesized NiCo2O4 nanosheets show a high specific capacitance of 3137 Fg(-1) at a current density of 2A g(-1), which is much greater than 1916 and 1251 F g(-1) of Co3O4 and NiO, respectively. Interestingly, the total specific capacitance of the NiCo2O4 is almost close to the sum of the specific capacitance of the NiO and Co3O4. Furthermore, a hybrid supercapacitor is configured with the NiCo2O4 nanosheets and the nitrogen- and sulfur-codoped reduced graphene oxide as the positive and negative electrodes, respectively. This hybrid supercapacitor delivers a maximum energy density of 33.64 W h kg(-1) at a power density of 1196 W kg(-1) and excellent long-term cyclic stability over 12,000 charge/discharge cycles at the enlarged voltage window of 1.5 V. The remarkable supercapacitive performances of the hybrid device are attributed to the interconnected porous structure of NiCo2O4 nanosheets and three-dimensional continuous macropores of codoped reduced graphene oxides. (C) 2018 Elsevier B.V. All rights reserved.