• 文献标题:   Highly Electrically Conducting Glass-Graphene Nanoplatelets Hybrid Coatings
  • 文献类型:   Article
  • 作  者:   GARCIA E, NISTAL A, KHALIFA A, ESSA Y, DE LA ESCALERA FM, OSENDI MI, MIRANZO P
  • 作者关键词:   hybrid coating, graphene nanoplatelet, heat resistant glas, thermal spraying, electrical conductivity, strain tolerance, electromagnetic interference shielding, thermal protection
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Inst Ceram Glass ICV CSIC
  • 被引频次:   6
  • DOI:   10.1021/acsami.5b02553
  • 出版年:   2015

▎ 摘  要

Hybrid coatings consisting of a heat resistant Y2O3Al2O3-SiO2 (YAS) glass containing 2.3 wt % of graphene nanoplatelets (GNPs) were developed by flame spraying homogeneous ceramic powders-GNP granules. Around 40% of the GNPs survived the high spraying temperatures and were distributed along the splat-interfaces, forming a percolated network. These YAS-GNP coatings are potentially interesting in thermal protection systems and electromagnetic interference shields for aerospace applications; therefore silicon carbide (SiC) materials at the forefront of those applications were employed as substrates. Whereas the YAS coatings are nonconductive, the YAS-GNP coatings showed in-plane electrical conductivity (similar to 10(2) S.m(-1)) for which a low percolation limit (below 3.6 vol %) is inferred. Indentation tests revealed the formation of a highly damaged indentation zone showing multiple shear displacements between adjacent splats probably favored by the graphene sheets location. The indentation radial cracks typically found in brittle glass coatings are not detected in the hybrid coatings that are also more compliant.