• 文献标题:   beta-Alanine-functionalized magnetic graphene oxide quantum dots: an efficient and recyclable heterogeneous basic catalyst for the synthesis of 1H-pyrazolo[1,2-b]phthalazine-5,10-dione and 2,3-dihydroquinazolin-4(1H)-one derivatives
  • 文献类型:   Article
  • 作  者:   ABBASABADI MK, AZARIFAR D
  • 作者关键词:   1hpyrazolo1 2b phthalazine5 10dione, 2 3dihydroquinazolin4 1h one, environmentally friendly nanomagnetic sheet, heterogeneous basic catalyst, magnetic betaalaninefunctionalized graphene oxide quantum dot
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Bu Ali Sina Univ
  • 被引频次:   1
  • DOI:   10.1002/aoc.5872 EA AUG 2020
  • 出版年:   2020

▎ 摘  要

In this research, we report a novel synthesis of magnetic beta-alanine-functionalized-graphene oxide quantum dots Fe3O4@GOQDs-N-(beta-alanine) as a recyclable and eco-friendly heterogeneous nanocatalyst. The catalytic efficiency of these nanosheets was explored as a basic catalyst for a one-pot three-component synthesis of various 1H-pyrazolo[1,2-b]phthalazine-5,10-dione and 2,3-dihydroquinazolin-4(1H)-one derivatives. The reactions proceeded smoothly under mild and green conditions to afford the respected products in excellent yields. The structure of this newly fabricated catalyst was successfully confirmed by different analytical techniques such as Fourier transform infrared spectroscopy, X-ray diffraction, field emission-scanning electron microscopy, high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, vibrating sample magnetometry, and thermogravimetric analysis. The stability and recyclability of the catalyst were examined by performing the model reaction in six consecutive runs. The recovered catalyst from the first run was directly used for the next runs with no significant loss of catalytic activity.