• 文献标题:   Synthesis and thermal stability, electrical conductivity and dielectric spectroscopic studies of poly (ethylene-co-vinyl alcohol)/graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   YASSIN AY, ABDELGHANY AM
  • 作者关键词:   graphene oxide, nanocomposite, activation energy, thermal stability, dielectric propertie, ac, dc conductivity
  • 出版物名称:   PHYSICA BCONDENSED MATTER
  • ISSN:   0921-4526 EI 1873-2135
  • 通讯作者地址:  
  • 被引频次:   18
  • DOI:   10.1016/j.physb.2020.412730 EA FEB 2021
  • 出版年:   2021

▎ 摘  要

A new nanocomposite was successfully synthesized by incorporating the prepared graphene oxide into poly (ethylene-co-vinyl alcohol) (EVOH) copolymer via simple solution casting method. XRD, FT-IR, SEM and TGA analysis were used to characterize the current nanocomposite. AC electrical transport properties of the nanocomposite were studied in the frequency range (10 Hz-1MHz) over the temperature range (298?423 K). The AC conductivity results were interpreted using jump relaxation model and were found to obey the universal double power law. The conduction mechanism inside the current samples has changed from non-overlapping small polaron tunneling to correlated barrier hopping. The calculated barrier height has indicated that the predominant charge carriers in the EVOH/GO nanocomposite are the single polarons and not bipolarons. The enhancement in ?ac of the EVOH-based nanocomposite, making these samples highly recommended for use in energy storage applications such as; electronic capacitors where materials with high dielectric constant and low dielectric loss are required.