• 文献标题:   New types of graphene-based membranes with molecular sieve properties for He, H-2 and H2O
  • 文献类型:   Article
  • 作  者:   VAN GESTEL T, BARTHEL J
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MEMBRANE SCIENCE
  • ISSN:   0376-7388 EI 1873-3123
  • 通讯作者地址:   Forschungszentrum Julich
  • 被引频次:   6
  • DOI:   10.1016/j.memsci.2018.02.034
  • 出版年:   2018

▎ 摘  要

Graphene oxide (GO) and graphene membranes were fabricated by dip-coating a GO dispersion on a specially designed 8YSZ mesoporous membrane. With the use of a reductive thermal treatment at 750 degrees C, it was possible to obtain a graphene membrane with permselectivities of 215, 80 and 170, for the gas pairs He/N-2, H-2/CO2 and H-2/N-2, respectively, and the H-2 permeance reached similar to 7 center dot 10(-8) mol m(-2) s(-1) Pa-1. High H2O permeance and selectivity was achieved by processing a GO membrane in air at 300 degrees C. In pervaporation with H2O/IPA mixtures (5% H2O), the resulting membrane selectively separated H2O (separation factor > 800) and a flux of 4-8 kg m(-2) h(-1) was achieved at 70 degrees C.