• 文献标题:   Mesoporous TiO2 nanosheets anchored on graphene for ultra long life Na-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG RF, WANG YK, ZHOU H, LANG JX, XU JJ, XIANG Y, DING SJ
  • 作者关键词:   sodiumion batterie, anatase tio2, graphene, nanosheet, ultra long life
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   10
  • DOI:   10.1088/1361-6528/aab562
  • 出版年:   2018

▎ 摘  要

Sodium-ion batteries, which have a similar electrochemical reaction mechanism to lithium-ion batteries, have been considered as one of the most potential lithium-ion battery alternatives due to the rich reserves of sodium. However, it is very hard to find appropriate electrode materials imputing the large radius of sodium-ion. TiO2 is particularly interesting as anodes for sodium-ion batteries due to their reasonable operation voltage, cost, and nontoxicity. To obtain a better electrochemical property, mesoporous TiO2 nanosheets (NSs)/reduced graphene oxide (rGO) composites have been synthesized via a scalable hydrothermal-solvothermal method with a subsequent calcination process. Benefitting from unique structure design, TiO2 NSs@rGO exhibits a superior cycle stability (90 mAh g(-1) after 10 000 cycles at a high current rate of 20 C) and satisfactory rate performance (97.3 mAh g(-1) at 25 C). To our knowledge, such ultra long cycle life has not previously been reported.