▎ 摘　　要

Nitrogen-doped nanoporous carbon/graphene networks (NPC/G) have been prepared by zeolitic imidazolate frameworks (ZIF-8) homogeneously encapsulated in graphene oxide (GO) networks, which were carbonized at high-temperature under a N-2 atmosphere and washed to get rid of impurities. The obtained NPC/G composites are highly graphitizing and exhibit a high specific surface area up to 703 m(2) g(-1). By optimizing the annealing conditions, the nanoporous frameworks derived from ZIF-8 can be effectively maintained, which are beneficial for electrolyte ion adsorption and transportation. Furthermore, the NPC/G composites are used as electrode materials for supercapacitive energy storage and show a high specific capacitance of 235 F g(-1) at a current density of 1 A g(-1), which is larger than that of NPCs and rGO. This provides a new route for designing novel structures to improve electrochemical performance. More interestingly, these electrode materials also present excellent rate capability and 85% retention of its initial capacitance after 1000 cycles in 1 M KOH aqueous solution.