• 文献标题:   In situ growth of sandwich-like NiMoO4 nanowires/reduced graphene oxide hybrid for high-performance lithium storage
  • 文献类型:   Article
  • 作  者:   ZHU G, XU HF, WANG HY, LU T, PAN LK, ZHANG L
  • 作者关键词:   in situ growth, sandwichlike, nimoo4, rgo hybrid, lithiumion batterie
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Suzhou Univ
  • 被引频次:   1
  • DOI:   10.1007/s11581-019-03016-2
  • 出版年:   2019

▎ 摘  要

Transition metal oxide electrodes, with rational structure as well as component design and combination with carbonaceous conductive support, are widely used in high-performance lithium-ion batteries (LIBs). Herein, NiMoO4 nanowires in situ decorated on reduced graphene oxide (NiMoO4/rGO) were synthesized through a facile hydrothermal and subsequent annealing method. Due to the enhanced electrical conductivity and buffering matrix provided by rGO and the synergistic effect between NiMoO4 and rGO, the resultant NiMoO4/rGO exhibits short ion transport pathways and improved diffusion kinetics. The results reveal that NiMoO4/rGO hybrid shows much improved lithium storage performances compared with pure NiMoO4 nanowires including a high specific capacity (1212.4 mAh g(-1) after 100 cycles at 0.2 A g(-1)), high rate capability (988.6 mAh g(-1) at 2 A g(-1) and 928.1 mAh g(-1) at 4 A g(-1)) and excellent cycling performance at high current density (1007.6 mAh g(-1) after 1000 cycles at 1 A g(-1)) when applied as anode material for LIBs, outperforming most of the reported metal molybdates-based electrodes. Besides, such excellent lithium storage performance, combined with the simple hydrothermal-annealing synthesis strategy, makes the NiMoO4/rGO a promising anode material for high-performance LIBs.