• 文献标题:   Amorphous CoS nanoparticle/reduced graphene oxide composite as high-performance anode material for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHU XM, JIANG XY, LIU XL, XIAO LF, AI XP, YANG HX, CAO YL
  • 作者关键词:   cos nanoparticle, amorphou, reduced graphene oxide, sodiumion battery, electron beam radiation
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   11
  • DOI:   10.1016/j.ceramint.2017.04.128
  • 出版年:   2017

▎ 摘  要

Transition metal sulfides have been proved as promising candidates of anode materials for sodium-ion batteries (SIBs) due to their high sodium storage capacity, low cost and enhanced safety. In this study, the amorphous CoS nanoparticle/reduced graphene oxide (CoS/rGO) composite has been fabricated by a facile one-step electron beam radiation route to in situ decorate amorphous CoS nanoparticle on the rGO nanosheets. Benefiting from the small particle size (similar to 2 nm), amorphous structure, and electronic conductive rGO nanosheets, the CoS/rGO nanocomposite exhibits high sodium storage capacity (440 mAh g(-1) at 100 mA g(-1)), excellent cycling stability (277 mAh g(-1) after 100 cycles at 200 mA g(-1), 79.6% capacity retention) and high rate capability (149.5 mAh g(-1) at 2 A g(-1)). The results provide a facile approach to fabricate promising amorphous and ultrafine metal sulfides for energy storage.