• 文献标题:   Impregnation of Cobalt on Graphene Sheet Using Liquid Phase Plasma Method for Lithium-Ion Batteries Application
  • 文献类型:   Article
  • 作  者:   KIM BH, PARK YK, AN KH, LEE H, JUNG SC
  • 作者关键词:   lithiumion battery, liquid phase plasma, graphene, cobalt oxide, electrochemical stability
  • 出版物名称:   SCIENCE OF ADVANCED MATERIALS
  • ISSN:   1947-2935 EI 1947-2943
  • 通讯作者地址:   Sunchon Natl Univ
  • 被引频次:   4
  • DOI:   10.1166/sam.2016.2887
  • 出版年:   2016

▎ 摘  要

The liquid phase plasma (LPP) method was applied to the impregnation of cobalt/graphene and cobalt oxide/graphene composites as the anode materials for lithium-ion batteries. Spherical cobalt and cobalt oxide nanoparticles, approximately 2 similar to 7-nm in size, were dispersed uniformly on the surface of the two-dimensional graphene sheet. The amount of cobalt oxide nanoparticles precipitated on the graphene sheet increased with increasing initial concentration of the cobalt precursor. Cobalt nanoparticles on the graphene sheet, which were composed of Co-0 and CoO, were oxidized by a thermal treatment to cobalt oxide nanoparticles composed of Co2O3 or Co3O4. The cycling stability and reversible lithium storage capacity were improved by thermal oxidation.