• 文献标题:   Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   ZHU XJ, ZHU YW, MURALI S, STOLLERS MD, RUOFF RS
  • 作者关键词:   reduced graphene oxide, fe2o3, anode, lithium ion battery, homogeneous coprecipitation
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   975
  • DOI:   10.1021/nn200493r
  • 出版年:   2011

▎ 摘  要

Reduced graphene oxide/Fe2O3 composite was prepared using a facile two-step synthesis by homogeneous coprecipitation and subsequent reduction of the G-O with hydrazine under microwave irradiation to yield reduced graphene oxide (RG-O) platelets decorated with Fe2O3 nanoparticles. As an anode material for Li-ion batteries, the RG-O/Fe2O3 composite exhibited discharge and charge capacities of 1693 and 1227 mAh/g, respectively, normalized to the mass of Fe2O3 In the composite (and 1355 and 982 mAh/g, respectively, based on the total mass of the composite), with good cycling performance and rate capability. Characterization shows that the Fe2O3 nanoparticles are uniformly distributed on the surface of the RG-O platelet in the composite. The total specific capacity of RG-O/Fe2O3 is higher than the sum of pure RG-O and nanoparticle Fe2O3, indicating a positive synergistic effect of RG-O and Fe2O3 on the improvement of electrochemical performance. The synthesis approach presents a promising route for a large-scale production of RG-O platelet/metal oxide nanoparticle composites as electrode materials for Li-ion batteries.