• 文献标题:   Experimental and simulation study on space charge characteristics of epoxy resin filled with graphene oxide
  • 文献类型:   Article
  • 作  者:   ZHANG SY, CHEN G, ZHANG HL, YAN JQ, LIU P, PENG ZR
  • 作者关键词:   carrier mobility, charge exchange, graphene compound, filled polymer, nanocomposite, resin, pulsed electroacoustic method, space charge, co, carrier mobility, hightemperature space charge, pulsed electroacoustic measurement, epoxybased nanocomposite, conductivity, hetero charge accumulation, singlelayer graphene oxide, charge migration, charge transport behaviour, epoxy resin, trap depth, charge distribution, trap density
  • 出版物名称:   IET SCIENCE MEASUREMENT TECHNOLOGY
  • ISSN:   1751-8822 EI 1751-8830
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   5
  • DOI:   10.1049/iet-smt.2018.5398
  • 出版年:   2019

▎ 摘  要

Graphene has attracted much attention due to its advanced properties. In previous work, the relationship between temperature and the conductivity of epoxy-based nanocomposite filled with graphene oxide has been experimentally studied. To understand the charge transport behaviour, the space charge characteristics at different temperatures and field strengths are measured with an improved pulsed electroacoustic measurement system, which is designed for high-temperature space charge measurement. From the measurement results, epoxy resin (ER) filled with multi-layer graphene oxide (MGO/ER) shows suppressed charge migration while ER filled with single-layer graphene oxide (SGO/ER) shows a hetero charge accumulation, which is assumed to be caused by the partial reduction of graphene oxide to graphene. Compared to pure ER, the apparent mobility of the nanocomposites is smaller while the trap depth and number of trapped charges are larger, which is probably caused by the introduction of traps. In the simulation, the relationship between mobility, trap depth, trap density and charge distribution are firstly studied. Then the calculated values of mobility and trap depth are given to the parameters to compare the simulated charge profiles with experiment results. The simulation results agree well qualitatively with the experimental results, giving some support for the proposed explanations.