• 文献标题:   Hybrid TiO2-Graphene nanoribbon photoanodes to improve the photoconversion efficiency of dye sensitized solar cells
  • 文献类型:   Article
  • 作  者:   AKILIMALI R, SELOPAL GS, BENETTI D, SERRANOESPARZA I, ALGARABEL PA, DE TERESA JM, WANG ZMM, STANSFIELD B, ZHAO HG, ROSEI F
  • 作者关键词:   graphene nanoribbon, dye sensitized solar cell, tio2gnr hybrid photoanode, electron transport, carrier recombination
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Inst Natl Rech Sci
  • 被引频次:   8
  • DOI:   10.1016/j.jpowsour.2018.06.044
  • 出版年:   2018

▎ 摘  要

We report the effect of incorporating different loadings of graphene nanoribbons (GNR) into a standard photoanode made of TiO2 sensitized with dye molecules. The GNRs are observed to significantly improve the photoconversion efficiency (PCE) of dye-sensitized solar cells (DSSCs). The TiO2-GNR hybrid photoanodes were prepared using the doctor-blade method. The presence of GNR in the composite photoanode was characterized by scanning electron microscopy, transmission electron microscopy and Raman spectroscopy. Our results highlight that, at an optimum loading of 0.005 wt%, GNR increases the PCE of DSSCs up to values 20% higher than the PCE of control devices. This improvement is mainly attributed to improved dye loading, enhanced electron lifetime and reduced carrier recombination, as confirmed by quantitative measurements of dye loading, transient photovoltage decay and electrochemical impedance spectroscopy results, respectively.