• 文献标题:   Bi2O2S nanosheets anchored on reduced graphene oxides as superior anodes for aqueous rechargeable alkaline batteries
  • 文献类型:   Article
  • 作  者:   LIU YL, LI MQ, WANG GG, DANG LY, LI F, YAN D, TAN ML, ZHANG HY, YANG HY
  • 作者关键词:   bi2o2s, aqueous rechargeable alkaline batterie, nanosheet, anode material, reduced graphene oxide
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.electacta.2022.140833 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

To achieve high-performance aqueous rechargeable alkaline batteries (ARABs), durable and high-rate anode materials should be developed. Bi-based materials have always been considered as promising anodes due to their enormous capacity, adequate negative operating voltage range, and three-electron redox characteristics. None-theless, the poor kinetics and low cycling stability of bi-based materials have severely limited their applications for ARABs. Here inspired by the unique structural characteristic of two-dimensional (2D) materials with a fast ion diffusion channel and relatively robust structure, 2D/2D Bi2O2S@rGO nanosheets were synthesized using a one-step hydrothermal process as the anode material for ARABs. At a current density of 1 A g-1, the as-optimized anodes exhibit a high specific capacity of 250.51 mAh g- 1. Using Bi2O2S@rGO NSs as the anode and (NiCo)9S8 as the cathode, the full cell exhibit a high energy density of 82.91 W h kg-1, a high power density of 7.59 kW kg-1, and excellent cycling stability, with a capacity retention rate of 92.74% after 5,000 cycles. This work could open up a way for environmentally friendly and high-performance anode materials.