• 文献标题:   Self-sustained solid -state exothermic reaction for scalable graphene production
  • 文献类型:   Article
  • 作  者:   YANG M, LIU JX, LI SK, ZHANG S, ZHUANG ZH, WANG YC, HE C
  • 作者关键词:   graphene, selfsustained exothermic reaction, energetic material, lithiumion battery
  • 出版物名称:   MATERIALS DESIGN
  • ISSN:   0264-1275 EI 1873-4197
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   0
  • DOI:   10.1016/j.matdes.2020.109135
  • 出版年:   2020

▎ 摘  要

Synthesis of graphene at high temperature offers an alternative route for large-scale production on a short time scale. Through the solid-state exothermic reaction of the polytetrafluoroethylene (PTFE)-Al energetic material, single and few-layer graphene having a lateral size in tens of nanometers are produced with an ultralow power consumption due to the self-sustained characteristics of the reaction. The graphene can directly disperse in ethanol to form stable dispersion and by evaluating in half-cell configuration, the graphene exhibits a stable cycling performance over 1000 cycles. The positive correlation between the dimension of the PTFE precursor and graphene demonstrates the feasibility of synthesizing powdered graphene in a controllable manner. (c) 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).