• 文献标题:   Synthesis and characterization of Li4Ti5O12/graphene composite as anode material with enhanced electrochemical performance
  • 文献类型:   Article
  • 作  者:   ZHANG Q, PENG WJ, WANG ZX, LI XH, XIONG XH, GUO HJ, WANG ZG, WU FX
  • 作者关键词:   anode material, graphene, rate capability, lithiumion batterie
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   15
  • DOI:   10.1007/s11581-012-0813-x
  • 出版年:   2013

▎ 摘  要

The use of graphene as a conductive additive to enhance the rate capability and cycle stability of Li4Ti5O12 electrode material has been demonstrated. Li4Ti5O12 and its composite with graphene (1.86 wt%) are prepared by ball milling and simple chemical method, respectively. Among the as-synthesized composites, Li4Ti5O12 particles uniformly clung to the graphene sheets. When used as an electrode material for lithium ion battery, the composite presents excellent rate performance and high cyclic stability. It is found that the composite displayed high-rate capacity of 118.7 mAh g(-1) at 20 degrees C. Furthermore, the composite exhibits good cycle stability, retaining over 96 % of its initial capacity after 50 cycles at 10 C. The excellent electrochemical performance is attributed to a decrease in the charge-transfer resistance.