• 文献标题:   Investigations on partially reduced graphene oxide capped sulfur/polyaniline composite as positive electrode material for lithium-sulfur battery
  • 文献类型:   Article
  • 作  者:   RAJKUMAR P, DIWAKAR K, GNANAMUTHU RM, SUBADEVI R, SIVAKUMAR M
  • 作者关键词:   lithium sulfur battery, graphene oxide, polyaniline
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Alagappa Univ
  • 被引频次:   3
  • DOI:   10.1088/2053-1591/ab2e59
  • 出版年:   2019

▎ 摘  要

A ternary sulfur (S)/polyaniline (PAni)/partially reduced graphene oxide (prGO) composite material has been prepared via simple heat treatment. The combined effect of prGO/PAni performs multiple roles like serving as a conducting additive and as a porous adsorbing agent to prevent dissolution of polysulfide in the composite. The prepared material has been characterized for its structural and morphological studies using x-ray diffraction, Fourier transform infrared spectroscopy, Raman analysis and Scanning electron microscopy. Electrochemical measurements have been studied by cyclic voltammetry and charge-discharge analyses with the potential window of 1.5-3.0 V. The S/PAni/prGO composite cathode delivers an initial discharge capacity of 972 mAh g(-1) at 0.1 C rate and it sustains 645 mAh g(-1) at 50th cycle. The improved electrochemical performance of S/PAni/prGO cathode in lithium sulfur battery is mainly attributed to the combined effect of partially reduced graphene oxide and polyaniline.