• 文献标题:   Facile Preparation of TiO2 Nanoclusters on Graphene Templates for Photodegradation of Organic Compounds
  • 文献类型:   Article
  • 作  者:   JIANG ZX, WANG MQ, CHENG H, LI J, HUSNU A, LV HB, YAO YT, SHAO L, HUANG YD, DONG MD
  • 作者关键词:   titanium dioxide, graphene, supercritical co2, nanocluster
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE TECHNOLOGY
  • ISSN:   1005-0302
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   3
  • DOI:   10.1016/j.jmst.2015.01.011
  • 出版年:   2015

▎ 摘  要

Graphene is the most attractive carbon-based material at present and attracting increasing attention as promising candidates for applications in numerous areas, because of its extraordinary chemical, thermal and mechanical properties. In this paper, we discussed an innovative and simple method to synthesize titanium dioxide (TiO2) nanoclusters, using graphene as a mid-step template not as a component of final product. Using this method, the graphene was firstly fully coated with TiO2 nanoparticles by the thermal decomposition of titanium (IV) isopropoxide in a supercritical carbon dioxide (SC-CO2) at 200 degrees C; the developed TiO2/graphene composites then were heated in an oxygen atmosphere. Eventually the TiO2 nanoclusters were obtained. The prepared TiO2 nanoclusters showed irregular features with high surface coverage, providing promises in a wide range of applications, especially for photo-degradation of organic compounds in aqueous solution under the radiation of UV-light. Copyright (C) 2015, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited. All rights reserved.