• 文献标题:   Preparation, characterization and properties of the ternary composite beta(2)-SiW11/polyaniline/graphene oxide
  • 文献类型:   Article
  • 作  者:   CAO R, MA RH, WEN Q, ZHANG CL, YANG MR
  • 作者关键词:   transitionmetal substituted polyoxometallate, graphene oxide, capture agent, photocatalytic
  • 出版物名称:   JOURNAL OF COORDINATION CHEMISTRY
  • ISSN:   0095-8972 EI 1029-0389
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1080/00958972.2021.2008377 EA NOV 2021
  • 出版年:   2022

▎ 摘  要

The composites beta(2)-SiW11/GO and beta(2)-SiW11/PANI/GO were prepared by using graphene oxide as a carrier. Properties of the composites were characterized by UV-visible spectroscopy (UV-vis), infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), scanning electron microscopy (SEM-EDS), transmission electron microscopy (TEM), N-2 adsorption desorption and thermal gravimetric analysis. Properties of the composites were investigated by using methyl violet simulated industrial wastewater. The results showed that this composite had photocatalytic activities for many dyes, and the activity was higher than that of Degussa P25(TiO2). The photocatalytic performance of beta(2)-SiW11/PANI/GO had a higher activity than that of PANI, beta(2)-SiW11 and beta(2)-SiW11/GO, with photodegradation reaching 95.98% under 30 W ultraviolet light for 150 min. The reaction kinetics for photocatalytic degradation of methyl violet followed a first-order process. The prepared composite was recyclable and the performance remained good. The possible mechanism of photocatalytic activity of dopant material is discussed and schematized.