• 文献标题:   Electronic transition from graphite to graphene via controlled movement of the top layer with scanning tunneling microscopy
  • 文献类型:   Article
  • 作  者:   XU P, YANG YR, QI D, BARBER SD, SCHOELZ JK, ACKERMAN ML, BELLAICHE L, THIBADO PM
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   2469-9950 EI 2469-9969
  • 通讯作者地址:   Univ Arkansas
  • 被引频次:   13
  • DOI:   10.1103/PhysRevB.86.085428
  • 出版年:   2012

▎ 摘  要

A series of measurements using a technique called electrostatic-manipulation scanning tunneling microscopy (EM-STM) were performed on a highly oriented pyrolytic graphite surface. The electrostatic interaction between the STM tip and the sample can be tuned to produce both reversible and irreversible large-scale movement of the graphite surface. Under this influence, atomic-resolution STM images reveal that a continuous electronic transition from triangular symmetry, where only alternate atoms are imaged, to hexagonal symmetry can be systematically controlled. Density functional theory (DFT) calculations reveal that this transition can be related to vertical displacements of the top layer of graphite relative to the bulk. Evidence for horizontal shifts in the top layer of graphite is also presented. Excellent agreement is found between experimental STM images and those simulated using DFT.