• 文献标题:   Mixed Transition-Metal Oxides on Reduced Graphene Oxide as a Selective Catalyst for Alkaline Oxygen Reduction
  • 文献类型:   Article
  • 作  者:   WOLF S, ROSCHGER M, GENORIO B, GARSTENAUER D, HACKER V
  • 作者关键词:  
  • 出版物名称:   ACS OMEGA
  • ISSN:   2470-1343
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acsomega.3c00615 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

The development of highly efficient, stable, and selective non-precious-metal catalysts for the oxygen reduction reaction (ORR) in alkaline fuel cell applications is essential. A novel nanocomposite of zinc-and cerium-modified cobalt-manganese oxide on reduced graphene oxide mixed with Vulcan carbon (ZnCe-CMO/rGO-VC) was prepared. Physicochemical characterization reveals uniform distribution of nanoparticles strongly anchored on the carbon support resulting in a high specific surface area with abundant active sites. Electrochemical analyses demonstrate a high selectivity in the presence of ethanol compared to commercial Pt/C and excellent ORR activity and stability with a limiting current density of -3.07 mA cm-2, onset and half-wave potentials of 0.91 and 0.83 V vs reversible hydrogen reference electrode (RHE), respectively, a high electron transfer number, and an outstanding stability of 91%. Such a catalyst could be an efficient and cost-effective alternative to modern noble -metal ORR catalysts in alkaline media.