• 文献标题:   Facile Preparation of Layered Ni(OH)(2)/Graphene Composite from Expanded Graphite
  • 文献类型:   Article
  • 作  者:   QU RJ, DAI Z, TANG SH, ZHU ZT, HAARBERG GM
  • 作者关键词:   expanded graphite, layed ni oh 2 /graphene, electrodeposition, supercapacitor, nickel nanoparticle
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Southwest Petr Univ
  • 被引频次:   5
  • DOI:   10.20964/2017.10.72
  • 出版年:   2017

▎ 摘  要

A layered Ni(OH)(2)/graphene composite was firstly prepared by electrochemical deposition of nickel nanoparticles between layers of expanded graphite in Ni2+ containing solution, and then the deposited nickel nanoparticles were converted into Ni(OH)(2) via cyclic voltammetry in 6 M KOH electrolyte. Images of transmission electron microscopy show that Ni(OH)(2) particles are uniformly distributed on graphene sheets with an average diameter of 6 nm. The Ni(OH)(2)/graphene composite with an areal loading of 5 mg cm(-2) demonstrates a maximum specific capacitance of 856 F g(-1) at 1 A g(-1), and 79 % of the specific capacitance can be retained after 2000 cycles at a current density of 10 A g(-1). Commercial expanded graphite is much cheaper than activated carbon and considerably much cheaper than graphene, therefore this technique is very promising for mass production of supercapacitor electrodes.