• 文献标题:   Functionalization of graphene oxide with naphthalenediimide diamine for high-performance cathode materials of lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   SONG YD, GAO YR, RONG HR, WEN H, SHA YY, ZHANG HP, LIU HJ, LIU Q
  • 作者关键词:  
  • 出版物名称:   SUSTAINABLE ENERGY FUELS
  • ISSN:   2398-4902
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   5
  • DOI:   10.1039/c7se00543a
  • 出版年:   2018

▎ 摘  要

Through the covalent bonding between naphthalenediimide diamine (NDIDA) and graphene oxide (GO), we synthesize NDIDA-functionalized graphene oxide (NDIDA-GO). The as-synthesized NDIDA-GO is characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and the Brunauer-Emmett-Teller surface area analysis. As a cathode material for lithium-ion batteries, within a voltage window of 4.5-1.5 V, NDIDA-GO exhibits a high specific capacity, good cyclic stability, and rate capability, keeping a specific capacity of 240 mA h g(-1) after 50 cycles at 50 mA g(-1). This work provides an effective route for the development of high-performance organic-based cathode materials for lithium-ion batteries.