• 文献标题:   Softened Elastic Response and Unzipping in Chemical Vapor Deposition Graphene Membranes
  • 文献类型:   Article
  • 作  者:   RUIZVARGAS CS, ZHUANG HLL, HUANG PY, VAN DER ZANDE AM, GARG S, MCEUEN PL, MULLER DA, HENNIG RG, PARK J
  • 作者关键词:   graphene, grain boundarie, afm, membrane, cvd, molecular dynamics simulation
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Cornell Univ
  • 被引频次:   213
  • DOI:   10.1021/nl200429f
  • 出版年:   2011

▎ 摘  要

We use atomic force microscopy to image grain boundaries and ripples in graphene membranes obtained by chemical vapor deposition. Nanoindentation measurements reveal that out-of-plane ripples effectively soften graphene's in-plane stiffness. Furthermore, grain boundaries significantly decrease the breaking strength of these membranes. Molecular dynamics simulations reveal that grain boundaries are especially weakening when subnanometer voids are present in the lattice. Finally, we demonstrate that two graphene membranes brought together form membranes with higher resistance to breaking.