• 文献标题:   Ultrafast synthesis of Mn0.8Co0.2CO3/graphene composite as anode material by microwave solvothermal strategy with enhanced Li storage properties
  • 文献类型:   Article
  • 作  者:   XIONG QQ, LOU JJ, ZHOU YJ, SHI SJ, JI ZG
  • 作者关键词:   ultrafast synthesi, solvothermal, carbon material, composite material, energy storage conversion, lithiumion battery
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Hangzhou Dianzi Univ
  • 被引频次:   7
  • DOI:   10.1016/j.matlet.2017.09.045
  • 出版年:   2018

▎ 摘  要

Carbonate is recently studied as anode material for lithium ion battery due to its relatively high capacity compared to relative oxides. In order to improve the time-efficiency of synthesis, an ultrafast solvothermal process assisted with microwave is carried out to obtain well-constructed Mn0.8Co0.2CO3/graphene composite as anode material for lithium ion batteries. The as-prepared Mn0.8Co0.2CO3/graphene composite with a graphene amount of 17.5 wt% exhibits a morphology of cubic particles in graphene without any impurity. Mn0.8Co0.2CO3/graphene delivers high initial charge capacities of 1033 mAh g(-1). And after 120 cycles, charge/discharge capacities of 737/735 mAh g(-1) are maintained at 0.2 A g(-1). Even at 2 A g(-1), the composite can still deliver high charge/discharge capacities of 500/501 mAh g(-1). It is promising to obtain carbonate/graphene anode materials rapidly through such ultrafast solvothermal process assisted by microwave for application. (C) 2017 Elsevier B.V. All rights reserved.