• 文献标题:   Supramolecular hydrogen-bonded polyolefin elastomer/modified graphene nanocomposites with near Infrared responsive shape memory and healing properties
  • 文献类型:   Article
  • 作  者:   KASHIF M, CHANG YW
  • 作者关键词:   supramolecular hydrogenbonded elastomer, graphene, infrared light response, shape memory effect, healing effect
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:   Hanyang Univ
  • 被引频次:   17
  • DOI:   10.1016/j.eurpolymj.2015.02.007
  • 出版年:   2015

▎ 摘  要

Small amounts (0.25-1 wt%) of octadecylamine modified graphene oxide (ODA-GO) were incorporated into a 3-amio-1,2,4-triazole (ATA) crosslinked maleated polyethylene-octene elastomer (ATA-POE), a structurally dynamic supramolecular hydrogen-bonded thermoplastic elastomer, via melt blending to prepare ATA-POE/ODA-GO nanocomposites. Field-emission scanning electron microscopy and X-ray diffraction analysis for the ATA-POE/ODA-GO composites revealed that the ODA-GO sheets were dispersed at the nanoscale level in the elastomer matrix which results in enhancement of the mechanical properties of the nanocomposites at low filler loadings. These nanocomposites exhibit both shape memory and scratch-healing effects under near infrared (NIR) light exposure. It was revealed from the results that ODA-GO acted as NIR-triggered nanoheaters as well as reinforcing filler for the elastomer matrix. (C) 2015 Elsevier Ltd. All rights reserved.