• 文献标题:   Optical Imaging and Spectroscopic Characterization of Self-Assembled Environmental Adsorbates on Graphene
  • 文献类型:   Article
  • 作  者:   GALLAGHER P, LI YL, WATANABE K, TANIGUCHI T, HEINZ TF, GOLDHABERGORDON D
  • 作者关键词:   graphene, adsorbate, selfassembly, polarized light, friction
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Stanford Univ
  • 被引频次:   4
  • DOI:   10.1021/acs.nanolett.8b00348
  • 出版年:   2018

▎ 摘  要

Topographic studies using scanning probes have found that graphene surfaces are often covered by micron-scale domains of periodic stripes with a 4 nm pitch. These stripes have been variously interpreted as structural ripples or as self-assembled adsorbates. We show that the stripe domains are optically anisotropic by imaging them using a polarization-contrast technique. Optical spectra between 1.1 and 2.8 eV reveal that the anisotropy in the in-plane dielectric function is predominantly real, reaching 0.6 for an assumed layer thickness of 0.3 nm. The spectra are incompatible with a rippled graphene sheet but would be quantitatively explained by the self-assembly of chainlike organic molecules into nanoscale stripes.