• 文献标题:   Co-sorption of Sr2+ and SeO42- as the surrogate of radionuclide by alginate-encapsulated graphene oxide-layered double hydroxide beads
  • 文献类型:   Article
  • 作  者:   GUO BL, KAMURA Y, KOILRAJ P, SASAKI K
  • 作者关键词:   graphene oxide, layered double hydroxide, alginates bead, column experiment, radionuclide
  • 出版物名称:   ENVIRONMENTAL RESEARCH
  • ISSN:   0013-9351 EI 1096-0953
  • 通讯作者地址:   Kyushu Univ
  • 被引频次:   0
  • DOI:   10.1016/j.envres.2020.109712
  • 出版年:   2020

▎ 摘  要

Graphene oxides (GO) and layered double hydroxides (LDHs) were applied to produce alginate beads for the remove of Sr-90(2+) and (SeO42-)-Se-79. The Freundlich isotherm indicated that the Sr2+ sorption were based on the energetically heterogeneous multilayer surfaces. In contrast, the sorption behavior of SeO42- fitted to the Langmuir adsorption isotherm models, indicating that the removal of SeO42- was caused by the ion-exchange of LDHs. The synthesized LDH/GO alginates beads were also applied for setting up small-bore adsorption columns with loading synthetic SeO42- and Sr2+ contaminated wastewater. Based on the water chemistry, the adsorbed amount of Sr2+ significantly increased after using alginates beads, which was attributed to the functional groups of either GO or alginic acid. The incorporated SeO42- was highly depended on the contents of fabricated LDHs in alginate beads. Specifically, the adsorption capacity of Sr2+ (0.85-0.91 mmol/g) on GO slightly increased after alginates fabrication. Therefore, it was deduced that this layered material was partially exfoliated during the manufacture and thus increased the sorption sites. Applications of LDH/GO alginates beads in the removal of both Sr2+ and SeO42- in water and soil treatment have a significant impact on the environmental remediation.