• 文献标题:   Defluoridation from aqueous solution by manganese oxide coated graphene oxide
  • 文献类型:   Article
  • 作  者:   LI YH, DU QJ, WANG JJ, LIU TH, SUN JK, WANG YH, WANG ZH, XIA YZ, XIA LH
  • 作者关键词:   graphene oxide, defluoridation, manganese oxide, adsorption, kinetic modeling
  • 出版物名称:   JOURNAL OF FLUORINE CHEMISTRY
  • ISSN:   0022-1139 EI 1873-3328
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   34
  • DOI:   10.1016/j.jfluchem.2013.01.028
  • 出版年:   2013

▎ 摘  要

A new adsorbent manganese oxide coated graphene oxide (MOGO) was synthesized and characterized by TEM, XRD, FTIR, and BET analysis. The effects of different parameters such as pH, adsorbent dose, contact time and temperature were studied to understand the adsorption behavior of the adsorbent under various conditions. Adsorption studies revealed that optimum removal of fluoride occurred in a pH range of 5.5-6.7. The Langmuir isotherm model demonstrated that the maximum fluoride adsorption capacity of MOGO was 11.93 mg/g and 8.34 times higher than that of GO. The kinetic adsorption data were analyzed using the pseudo first-order model, the pseudo second-order model and the intra-particle diffusion model. Thermodynamic adsorption results showed that adsorption of fluoride by MOGO was a spontaneous and endothermic process. (C) 2013 Elsevier B.V. All rights reserved.