• 文献标题:   Synthesis and characterization of poly(ethylene tetrasulfide)/graphene oxide nanocomposites by in situ polymerization method
  • 文献类型:   Article
  • 作  者:   KAZEROUNI SS, KALAEE M, SHARIF F, MAZINANI S
  • 作者关键词:   poly alkyltetrasulfide, graphene oxide, nanocomposite, interfacial polycondensation
  • 出版物名称:   JOURNAL OF SULFUR CHEMISTRY
  • ISSN:   1741-5993 EI 1741-6000
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   4
  • DOI:   10.1080/17415993.2016.1139114
  • 出版年:   2016

▎ 摘  要

Poly(ethylene tetrasulfide) (PSP) is synthesized via interfacial polycondensation of 1,2 dichloroethane and sodium tetrasulfide, in the presence of graphene oxide (GO). This process resulted in homogeneously dispersed PSP/GO nanocomposites. Nanocomposites of 0.3 and 0.5wt% of GO are synthesized and their morphology, chemical characteristics behavior are studied employing field emission scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques. Thermal characterization of composites is performed by differential scanning calorimetry and thermogravimetry analysis. Results indicate that the addition of only small amounts (0.5wt%) of well-dispersed GO can increase the melting point more than 16 degrees C resulting in better thermal properties for the composite. The solubility of nanocomposite is also studied and results show that the solubility depends on solvent concentration in addition to reinforcement (GO) deals. [GRAPHICS]