• 文献标题:   Graphene-coated mesoporous carbon/sulfur cathode with enhanced cycling stability
  • 文献类型:   Article
  • 作  者:   ZHAO XY, TU JP, LU Y, CAI JB, ZHANG YJ, WANG XL, GU CD
  • 作者关键词:   sulfur cathode, mesoporous carbon, graphene, cycling stability, lithiumsulfur battery
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   65
  • DOI:   10.1016/j.electacta.2013.09.078
  • 出版年:   2013

▎ 摘  要

A self-assembly approach is used to fabricate a graphene-coated mesoporous carbon/sulfur composite. The graphene coating on the surface of the composite is 15-20 nm in thickness, and sulfur is well dispersed in the pores of mesoporous carbon and the interfaces between the mesoporous carbon and graphene sheets after a heat treatment at 300 degrees C. The graphene coating helps to increase the sulfur content and retard the diffusion of polysulfides. The galvanostatic charge-discharge tests show that the graphene-coated sulfur electrode presents good cycling stability. Specific discharge capacities up to 650 mAh g(-1) over 100 cycles at 0.1 C is achieved with enhanced coulombic efficiency, representing a promising cathode material for lithium-sulfur battery. (C) 2013 Elsevier Ltd. All rights reserved.