• 文献标题:   Effects of graphene on thermal properties and thermal stability of polycarbonate/graphene nanocomposite
  • 文献类型:   Article
  • 作  者:   SOHEL MA, MONDAL A, ARIF PM, THOMAS S, SENGUPTA A
  • 作者关键词:   polycarbonate, graphene, polymer nanocomposite, thermal propertie, thermal degradation, activation energy
  • 出版物名称:   JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
  • ISSN:   0892-7057 EI 1530-7980
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1177/0892705721997887 EA APR 2021
  • 出版年:   2023

▎ 摘  要

Polycarbonate (PC) /graphene nanocomposite was prepared using multilayer graphene (MLG) with loadings of 0.5, 1, and 3 wt% via melt mixing process. Morphological, structural, and thermal properties of the PC/MLG nanocomposites are investigated to look into the influence of MLG on the nanocomposite. A significant increase (similar to 6.4 degrees C) in glass transition temperature is observed upon the addition of 3 wt% of MLG into the polycarbonate matrix. This increase in glass transition temperature may be due to the interaction between the MLG and polycarbonate polymer matrix. The specific heat capacity of pure PC and PC/MLG nanocomposites varies linearly with temperature below their glass transition. Upon the addition of MLGs, the overall thermal stability of PC/MLG nanocomposites increases with MLG loadings. A maximum increase about 29.23 degrees C in T (onset) of thermal decomposition is observed in PC/MLG nanocomposite having 3 wt% of MLG loading. The activation energy (E-a ) of thermal decomposition is also calculated by kinetic analysis of thermal decomposition of the PC/MLG nanocomposites using Horowitz-Metzger and Broido's methods.