• 文献标题:   Modulation of Viscoelastic and Absorption Properties of Poly(vinyl alcohol)-graphene Oxide Composites
  • 文献类型:   Article
  • 作  者:   LEI Y, BOUCENNA I, THEVENET V, DRAGOE D, PONTON A
  • 作者关键词:   graphene oxide, poly vinyl alcohol, polymer nanocomposite, rheology, absorption, swelling
  • 出版物名称:   ACS APPLIED POLYMER MATERIALS
  • ISSN:   2637-6105
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1021/acsapm.1c00872 EA AUG 2021
  • 出版年:   2021

▎ 摘  要

PVA (poly(vinyl alcohol))/GO (graphene oxide) composites were prepared by mixing the PVA aqueous solution and GO aqueous dispersion through the freezing-thawing method. The morphology and chemical structure of GO and composites were investigated by scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. Viscoelastic and swelling properties and absorption capacities of cationic dye methylene blue (MB) were studied as a function of initial concentration of PVA and GO and the number of freezing-thawing cycles. The highest improvement in linear viscoelastic properties of PVA/GO composites was observed with the increase of GO concentration. Experimental data of the kinetic study of MB absorption were well fitted by the pseudo-first-order kinetic model and it was clearly shown that the greatest enhancement of MB absorption was also achieved by increasing the GO concentration. A correlation between swelling, absorption, and viscoelastic and structural properties of PVA/GO composites was proposed.