• 文献标题:   Dry transfer of graphene to dielectrics and flexible substrates using polyimide as a transparent and stable intermediate layer
  • 文献类型:   Article
  • 作  者:   MARCHENA M, WAGNER F, ARLIGUIE T, ZHU B, JOHNSON B, FERNANDEZ M, CHEN TL, CHANG T, LEE R, PRUNERI V, MAZUMDER P
  • 作者关键词:   graphene, dry transfer, polyimide, hot pres, laminator, cu recycling, graphene transfer
  • 出版物名称:   2D MATERIALS
  • ISSN:   2053-1583
  • 通讯作者地址:   Barcelona Inst Sci Technol
  • 被引频次:   6
  • DOI:   10.1088/2053-1583/aac12d
  • 出版年:   2018

▎ 摘  要

We demonstrate the direct transfer of graphene from Cu foil to rigid and flexible substrates, such as glass and PET, using as an intermediate layer a thin film of polyimide (PI) mixed with an aminosilane (3-aminopropyltrimethoxysilane) or only PI, respectively. While the dry removal of graphene by an adhesive has been previously demonstrated-being removed from graphite by scotch tape or from a Cu foil by thick epoxy (similar to 20 mu m) on Si-our work is the first step towards making a substrate ready for device fabrication using the polymer-free technique. Our approach leads to an article that is transparent, thermally stable-up to 350 degrees C -and free of polymer residues on the device side of the graphene, which is contrary to the case of the standard wet-transfer process using PMMA. Also, in addition to previous novelty, our technique is fast and easier by using current industrial technology-a hot press and a laminator-with Cu recycling by its mechanical peel-off; it provides high interfacial stability in aqueous media and it is not restricted to a specific material-polyimide and polyamic acids can be used. All the previous reasons demonstrate a feasible process that enables device fabrication.