• 文献标题:   Adsorptive removal of Sr(II) from aqueous solution by polyvinyl alcohol/graphene oxide aerogel
  • 文献类型:   Article
  • 作  者:   HUO JB, YU GC, WANG JL
  • 作者关键词:   pva/go, adsorption, radionuclide, complexation, interaction
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:  
  • 被引频次:   24
  • DOI:   10.1016/j.chemosphere.2021.130492 EA APR 2021
  • 出版年:   2021

▎ 摘  要

In this study, a new adsorbent, polyvinyl alcohol (PVA) and graphene oxide (GO), was prepared, characterized and used for the removal of Sr2+ from aqueous solution. In PVA/GO composite, the interlamellar spacing of adjacent GO layers was dramatically enlarged due to the intercalation of PVA molecules, such a unique architecture significantly mitigated the aggregation of GO layers, which facilitated the accessible exposure of active sites and the mass transfer of strontium ions (Sr2+), thus enhancing the adsorption capacity toward Sr2+. The adsorption of Sr2+ by PVA/GO composite conformed to the pseudo second-order kinetic model (R-2 = 0.9994), the Langmuir model (R-2 = 0.9042), and the Freundlich model (R-2 = 0.9598). The complexation interaction between Sr2+ and oxygen atoms/p-electron domain of PVA/GO composite was primarily responsible for the adsorption mechanism, based on the characterization results of X-ray photoelectron spectroscopy (XPS), scanning electron microscope equipped with energy dispersion spectroscopy (SEM-EDS) and powder X-ray diffraction (PXRD). (C) 2021 Elsevier Ltd. All rights reserved.