▎ 摘　　要

Although graphene has aroused considerable interest in the thermal conductive enhancement of polymer composites for its superb intrinsic thermal conductivity, the enhancement efficiency is still limited by its productioninduced defects, misalignment and intense phonon interface scattering. Herein, the three-dimensional (3D) polydopamine-graphene foam (PGF) with high orientation and good interfacial bonding has been prepared by electro-exfoliation, surface modification and unidirectional-freezing. This unique structure imparts excellent thermal conductivity, electrical insulation and good mechanical property to the PGF/epoxy (PGF/EP) composite. The highly arranged and compact stacked PDA-graphene sheets bound by metal ions provide heat conduction paths for effective phonon transport within the matrix. The manufactured PGF/EP shows enhanced throughplane thermal conductivity of 3.48 W/m.K with 3.02 vol% of PGF, excellent surface & volume electrical resistivity (2.7 x 10(11) Omega and 1.65 x 10(11) Omega.cm) and high mechanical strength (82.74 MPa), as well as the outstanding heat dissipation performance. Therefore, the PGF/EP composites prepared in the present study have a broad application prospect in advanced electronic packaging materials.