• 文献标题:   Covalent surface modification of chemically derived graphene and its application as supercapacitor electrode material
  • 文献类型:   Article
  • 作  者:   JANA M, KHANRA P, MURMU NC, SAMANTA P, LEE JH, KUILA T
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   45
  • DOI:   10.1039/c3cp54510e
  • 出版年:   2014

▎ 摘  要

A simple and effective method using 6-amino-4-hydroxy-2-naphthalenesulfonic acid (ANS) for the synthesis of water dispersible graphene has been described. Ultraviolet-visible (UV-vis) spectroscopy reveals that ANS-modified reduced graphene oxide (ANS-rGO) obeys Beers law at moderate concentrations. Fourier transform infrared and X-ray photoelectron spectroscopies provide quantitative information regarding the removal of oxygen functional groups from graphene oxide (GO) and the appearance of new functionalities in ANS-rGO. The electrochemical performances of ANS-rGO have been determined by cyclic voltammetry, charge-discharge and electrochemical impedance spectroscopy analysis. Charge-discharge experiments show that ANS-rGO is an outstanding supercapacitor electrode material due to its high specific capacitance (375 F g (-1) at a current density of 1.3 A g(-1)) and very good electrochemical cyclic stability (similar to 97.5% retention in specific capacitance after 1000 charge-discharge cycles). ANS-rGO exhibits promising characteristics with a very high power density (1328 W kg(-1)) and energy density (213 W h kg(-1)).