• 文献标题:   Fabricating of high-performance functional graphene fibers for micro-capacitive energy storage
  • 文献类型:   Article
  • 作  者:   FAN TJ, ZHAO CY, XIAO ZQ, GUO FJ, CAI KY, LIN H, LIU YD, MENG H, MIN Y, EPSTEIN AJ
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Peking Univ
  • 被引频次:   9
  • DOI:   10.1038/srep29534
  • 出版年:   2016

▎ 摘  要

Although graphene is a typical two dimensional materials, it has converted to multi-dimensional materials with many unique properties. As an example, the one dimensional graphene fiber is fabricated by utilizing ionic liquid as coagulation and functional diamines as cross-linkers to connect graphene oxide layers. The fibers show excellent mechanical properties and superior electrical performance. The tensile strength of the resultant fibers reaches similar to 729 MPa after a super high temperature thermal annealing treatment at 2800 degrees C. Additionally, quasi-solid-state flexible micro-capacitors are fabricated with promising result on energy storage. The device show a specific volumetric capacity as high as similar to 225 F/cm(3) (measured at 103.5 mA cm(-3) in a three-electrode cell), as well as a long cycle life of 2000 times. The initial results indicate that these fibers will be a good candidate to replace energy storage devices for miniaturized portable electronic applications.