• 文献标题:   Study on Oxidation State Dependent Electrocatalytic Ability for I-/I-3(-) Redox Reaction of Reduced Graphene Oxides
  • 文献类型:   Article
  • 作  者:   YEH MH, LIN LY, HUANG TY, CHUANG HM, CHU CW, HO KC
  • 作者关键词:   counter electrode, dyesensitized solar cell, electrocatalytic ability, photothermal reduction proces, reduced graphene oxide
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   6
  • DOI:   10.1002/elan.201300321
  • 出版年:   2014

▎ 摘  要

The influence of oxidation states on electrocatalytic abilities for I-3(-) reduction is discussed for reduced graphene oxide (rGO), which is a promising catalyst of counter electrodes for dye-sensitized solar cells (DSSCs). The oxidation states of rGO can be controlled via a photothermal reduction process by varying exposure times. The results reveal that the rGO with lower oxidation state shows smaller charge transfer resistance at the electrode/electrolyte interface and better electrocatalytic ability attributed to higher standard heterogeneous rate constant (k(0)) and reasonable electrochemical surface area (A(e)) for I-3(-) reduction, both are quantitatively determined by a rotating disk electrode system using the Koutecky-Levich equation.