• 文献标题:   Electrochemical Behavior of Graphene/ZnO Nanofllowers Synthesized by an Efficient and Facile Two-Step Technique
  • 文献类型:   Article
  • 作  者:   ZHANG Y, LIU GJ, YU FH
  • 作者关键词:   graphene/zno nanofllower, electrochemical impedance spectroscopy, cyclic voltammetry, photoluminescence spectroscopy, photocatalytic activity
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Changchun Normal Univ
  • 被引频次:   0
  • DOI:   10.20964/2019.07.78
  • 出版年:   2019

▎ 摘  要

An efficient and simple route was advanced to uniformly synthesize graphene/ZnO nanofllowers and an electrochemical impedance spectroscopy (EIS) technique was used to investigate the electrical properties. X-ray diffraction patterns indicated a broad and strong peak at 26 degrees value, which conformed with the graphene (002) plane. A very strong Raman band appeared at 1,594 and 1,358 cm(-1), that corresponded to the independent G and D bands, respectively. The photoluminescence results show that the graphene/ZnO nanostructures has a lower electrons/holes recombination rate under UV light irradiation, that may be attributed to graphene sheets in graphene/ZnO nanoflowers becoming the separation mechanisms of the photogenerated electrons/holes. Cyclic voltammetry plots indicate approximately rectangular shape, showing perfect supercapacitive behavior. The charge transfer resistance in the graphene/ZnO nanoflower electrode is 175 k Omega, which is considerably smaller than those of ZnO nanostructures (684 k Omega) electrode, demonstrating the better conductivity in the graphene/ZnO nanoflower electrode. The graphene/ZnO nanoflowers showed excellent photocatalytic activity for the degradation of MB under the visible light which can be ascribed to the high absorption intensity of graphene/ZnO nanoflowers in visible light region.