• 文献标题:   Low temperature selective catalytic reduction of NOx with NH3 with improved SO2 and water resistance by using N-doped graphene dots-CuO-CeO2 nano-heterostructures modified vanadate catalysts
  • 文献类型:   Article
  • 作  者:   CHOI SY, PURBIA R, KIM HJ, KIM JK, KIM SW, MO J, YE B, JEONG B, LEE DH, KIM D, PARK H, KIM HD, BAIK JM
  • 作者关键词:   ndoped graphene quantum dot, cuoceo2, nh3scr, lowtemperature, vanadate, so2 water resistance
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.apsusc.2023.157088 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

Herein, we report a facile strategy for efficient NH3-SCR catalytic performance of vanadate-based catalysts with superior sulfur and water resistance at low temperature (<200 degrees C). The catalyst design strategy is based on the selective adsorption of NO2 via the functionalization of N-doped graphene quantum dots (N-GQDs) and fast-SCR via the functionalization of CuO-CeO2 (CuCe) on 4V1W/Ti catalysts. The impregnation of 1 wt% N-GQDs and 2.8 wt% CuCe leads to more surface acid sites and facilitate the strong interaction between Cu-Ce-V oxides, thus improving NOx adsorption and improved redox process in low temperature ranges (180-220 degrees C). The synthe-sized CuCe-N-GQD-4V1W/Ti catalyst shows high DeNOx activity over 92 % with excellent N2 selectivity and SO2/H2O resistance at 200 degrees C. In situ diffuse reflectance Fourier transform analysis confirmed the Eley-Rideal SCR reaction pathway over the CuCe-N-GQDs-4V1W/Ti catalyst.