• 文献标题:   Graphene Oxide Nanosheets as An Efficient and Reusable Sorbents for Eosin Yellow Dye Removal from Aqueous Solutions
  • 文献类型:   Article
  • 作  者:   VEERAKUMAR P, THARINI J, RAMAKRISHNAN M, MUTHUSELVAM IP, LIN KC
  • 作者关键词:   adsorption, electrostatic interaction, eosin yellow, graphene oxide nanosheet, hydrogen bonding
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   9
  • DOI:   10.1002/slct.201700281
  • 出版年:   2017

▎ 摘  要

In this study, 2D graphene oxide nanosheets (GONS) were synthesized and characterized by XRD, Raman, SEM, FE-SEM, TEM, XPS, TGA, UV-vis and FTIR spectral techniques. The efficiency of eosin yellow (EY) dye adsorption on the GONS under various experimental parameters such as contact time, pH and temperature was investigated. Adsorption kinetic data were characterized appropriately using pseudo second-order-kinetics and intraparticle diffusion methods. Free energy of adsorption (Delta G(0)), enthalpy (Delta H-0), entropy (Delta S-0) changes, activation energy and Arrhenius factors were also calculated. The endothermic and spontaneous nature of the adsorption process was confirmed by the positive value of the enthalpy change (DH0) and the negative value of free energy change (DG(0)). The adsorption mechanism was investigated by FTIR spectra of GONS before and after adsorption of EY dye molecules. The remarkable adsorption capacity of EY onto the GONS can be attributed to the various adsorption interaction mechanisms such as hydrogen bonding, p-p electron, and electrostatic interactions. The maximum adsorption capacity for EY was calculated to be 217.33 mg g(-1.)